Well I was looking at doing my Combi as I am solar PV installer & want unvented cylinder installed with twin coil this way can have solar thermal & solar PV & install proportional heating controller.
The way I was going to do this was to install 2 motorised valves s plan layout one for heating one for hot water, this would make the combi into two heating zones but using one zone for hot water side (indirect cylinder).
This way valve would be controlled via the cylinder stat & if required but not sure till I installed it to see what would happen I could install 2 small relays & go through each coil so other would not work whilst other was on.
Have done something similar with a swimming pool as we had 2 pumps on the system & boiler running through a heat exchanger,
if one relay was in this would cut the power to the other coil, but also the other would not cut in until the first engaged was satisfied.
I would then install my 3rd heating zone which do my underfloor heating in the kitchen this would go through heat exchanger unit so when hot water is satisfied it would divert to underfloor heating if required from the heating controller or boiler, complex but I like heating & puzzles like that.
Hope the aboves makes sense?
But mine would only be until my combi was laid to rest then I would do this all through systems boiler.