But it's much more fun this way! In fact Danfoss 3 port zone valve wiring is a known entity and has stayed the same luckily even for 30+ years!
As per
@freddo 's comments:
Grey is Hot Water Off
Brown/White is Heating On
Blue is Neutral
and Orange is the output signal to ask the boiler to fire up.
View attachment 105004
So with 100% certainty we can say that with the Heating set to ON and stat all the way up then 2 and 3 should measure 230v to Neutral (marked)
I agree with Brian and Freddo that 1 is the controller asking for heat. So this should also measure 230v to Neutral.
Obviously this needs doing very carefully.
That will quickly reveal what is going on.