I suppose the first possibility is the photo-switch(PS) is defective which I will cover shortly.
First the wiring:
a. For the photo-voltaic (PV) panel, batteries, DC-DC converter and load, red is positive(+) and black is (-).
b. For the PS, the input should be wired black as positive(+), and white as (-) and the red is a switched positive(+) output.
c. The DC-DC converter is connected between the red and the white of the PS.
d. The butterfly is connected such that its positive goes to the yellow of the DC-DC converter and its black to the black of the converter.
Now back to the PS. There is a single screw holding the lid in place. Please unscrew it and then carefully withdraw the circuit board. Before you do anything else could you take some photos of the top and bottom of the board?
You should see a component called a photoresistor which is similar to this:
View attachment 52841
To check the circuit is working, could you connect up your circuit and place a multi-meter if you have one set to read dc voltage and 12-20V across the red and black of the PS. With daylight shining on the photo-resistor the output should be zero Volts.
Using a short length of single core wire, strip the insulation by 5mm of each end, and then carefully use this wire to short out the photo-resistor by attaching it across the two wire leads to the photo-resistor. Wait and listen carefully for the click of the relay. Do this a few times. If you hear no click of the relay then it indicates the circuit is defective in some way. If you do hear a click check then for a 12V reading on you multi-meter; if there is 12V then the PS is working. If the output remains at zero Volts even though you have heard the relay click then this indicates a fault with the board.
Be very careful not to accidentally touch any other contacts when you short out the photo-resistor because it could cause some damage.
Let me know what you find out.
Marconi