For multicore cables I tend to label the line conductors and then put in the neutral and cpc for each physical cable and then refer to the labelling for each line to place in the OCPDs. However if you have say a small domestic board with cooker, ring, lights on one side and immersion, ring, lights on the other the size of cables makes it obvious and you only need to ensure the immersion is separate from the ring.
If you are not cable tying up the cores and not doing overly neat bunches of cores then just pulling on the line as you prepare to terminate should move the corresponding neutral, but it is a bit hit and miss.
Identification is probably a good idea in all cases, it can be done without labelling on boards so long as you are paying attention and have a good memory however it is generally better to ensure you are correct.