Green gunge (also known as green goo) is sometimes seen exuding from the ends of older PVC insulated and sheathed cable. It is normally seen in cables made in the 1960s and 1970s, caused by the addition of an anti-oxidant added to the insulation mix, ironically, to extend the temperature range of the cable. This particular anti-oxidant is not use in modern PVC cables, because an unintended consequence of its use was to increase green goo production in heat stressed cables.
Its origin is the plasticiser used to provide flexibility in the PVC polymer compound. This is generally di-octyl phthalate, which over time or with excessive heat has reacted with the copper conductors to produce copper phthalate (hence the green colour) suspended in the liquid plasticiser.
[FONT=&]Although there does not appear to be a problem with the electrical performance or safety of the cable itself, any exuded gunge should be removed as it can cause corrosion or affect the action of switches and terminations, potentially resulting in tracking / overheating. It can also cause cosmetic problems such as staining. Although it is possible to clean-up local isolated extrusions with soft cloths soaked Mentholated Spirit, this is only likely to be a temporary solution as further leakage will continue. The affected circuits should be rewired as soon as possible.
There is evidence to suggest that high ambient temperatures accelerate the process. The exudate is of low flammability and low toxicity. Although unsightly, it does not reduce the electrical integrity of the conductor or the insulation. However, the green goo may have detrimental effects on both accessories (in appearance and functionality) and their surrounding decorative finishes. Unfortunately, where an installation is seriously affected by the deficiency, the only practicable solution is to rewire the premises and replace any damaged electrical equipment.
There are Health and Safety issues of retaining, working with and the disposal of contaminated wiring and accessories. As the material is a health concern, it should be handled with care – gloves should be worn at all times and waste disposed of properly. Deposits of the product must not be permitted to be exposed for causal contact, particularly in areas accessible to children.
In cases where a property is to be completely rewired, redundant materials should be disconnected and removed from site. Di-isoctyl phthalate is a toxic substance and suitable protective clothing should be worn when handling waste materials. Special attention should be paid to personal hygiene when working on contaminated installations. Waste should be disposed of in suitable labelled bags or containers and collected by registered Waste Disposal Contractors.[/FONT]