Good contractors would only install material for which they had, or could reliably obtain, traceable approvals. In the event of any comeback, their position is clear regarding the boundary between their responisibilities and those of the manufacturer. If your equipment is CE-marked, it doesn't matter that you made it, you can ask him to install it and his responsibilities are unchanged. Some contractors will however balk at fitting items that they consider less satisfactory than their normal choice. If your equipment does not carry the necessary approvals, e.g. because it's a prototype or demo model, then a contractor might not want to install it.
If you want to install equipment for the supply of electrical energy yourself, then it might need to comply with BS7671. A micropower sensor cable would not, an ELV circuit carrying 10A to lighting fixtures certainly would. The onus will be on you to provide the certification that it does. This should be no problem for you, as you will understand the requirements and can fill in the certificate. However, some would consider the load side of an un-pluggable CE-marked PSU brick not to be part of the fixed installation. If that is in fact the case, then once the electrician has laid on the supply to the brick, you can do whatever you like as far as BS7671 is concerned.