If the breaker says 63A on the front then that's the current it will carry without tripping. Does the breaker have a test button on it? If it does then you can use it for RCD protection but you'll need another breaker in the circuit for overload protection. It's worth noting that the MCB you use for overload protection is rated according to the supply cabling you're using, not necessarily the appliance on the end of it, ie the hot tub.