Is this a flat Manda ? As I would say that your riser cable is MICC/Pyro, as that looks to me to be a pyro terminating into that white header box, which as a seal on it, and most likely as a BS 1361 fuse inside it.
You also seem to have an upfront RCD from the meter before it goes into the CU, so I dont think it will be a TNC-S. From that white header box you look to have a really small 1.5mm earth to the BMT, which should be changed as its unprotected and not mechanically protected.
Now becasue you have an RCD there, by the way what size is it 100mA or 30mA, as you also seem to have an RCD in the CU. I think what as happened , the house will have a TN-S supply and they may not be able to achieve good Zs results on the final circuits and so fitted an upfront RCD providing protection.
Now if you mums is a flat you will have to find where that Ze was taken, was it at the origin where it should be, or was it at your mums board where it would be a Zdb. If it was at your mums board and it is a flat then that 0.22 is quite easily got due to parallel paths, can you give us a little more info as I might be well out lol