There used to be a specialised test kit to test these VOELCB's, i haven't personally seen one for nearly 30 years!! You basically don't have a choice in this matter, the old ELCB unit you have has been discontinued and you have no-means of testing it's values or it's efficiency. So the only course open to you, is to replace to present unit with a modern day equivalent, a RCD device. Not only will a RCD be a suitable replacement, it's protection level will be a vast improvement over the existing unit.
There is no reason, why at this time, you can't provide an RCD device for each of the supplies you talk about, which will further improve the protection afforded to this installation. As the VOELCB's were never known to be reliable, ....RCD's also, are not ''totally'' reliable, but compared to those old voltage operated units there isn't any comparison, an RCD outclasses them hands down.