Which tech manual?
In the Inspection, testing and certification guide I have seen that they point to "BS7430: Code of practice for earthing which suggests that a value of earth electrode resistance exceeding 100 ohms MAY be unstable."
The NICEIC themselves have never required a max value of 100 ohms for an earth rod, simples.
Historically, I don't think this is correct , however, you're right about the NICEIC stating that 200 ohms as the acceptable value as opposed to 100 ohms in both the training books i have.
apologies for the misunderstanding