There are meters with an 'alert' function, that makes a beeping noise and/ or flashes up 'LEAD' if you select a voltage range with red lead still in the current socket. Of course, if you also leave the meter on a current range and try to measure the voltage, that's no help.
But what are these people doing? I swap the leads on mine from current to voltage many, many times a day, every day, and haven't made this mistake for a decade or more. You need to drill into them the significance of checking the connections and settings for every setup bar none.
It's a good job they aren't trying to use a vintage valve tester. You can destroy a valuable AVO VCM instantly (beyond economic repair as the special panel meters haven't been made for years) just by turning one of its dials one click too far. FWIW the girls who used to help out on a Saturday never seemed to have any difficulty using them accurately.
Was thinking about your answer and yes you have summed it up completely.
“You haven’t made this mistake for a decade or more”.
Trouble is these are mainly brand new engineers on short courses and they probably won’t make the mistake again for a decade or more, how do I stop them doing their first and last time at my expense ️️Lol