Anything connected in series with battery leads will degrade starting performance at least very slightly, by adding resistance to a circuit that has to carry hundreds of amps with very little voltage drop. Low-cost battery isolators do work, but can be prone to excessive resistance. If you do want an isolator, make sure it is a good one, use nice heavy cable and make the connections properly (e.g. proper crimp lugs crimped with the right tool). High resistance can also decrease charging performance (where the maximum permissible drop is in the order of 0.1V). Also note that some electrical systems can be damaged if the battery is accidentally isolated while the engine is running.
An ordinary relay is not the way to go. Because of the heavy starting currents it must carry, a contactor or relay large enough for the job uses too much power for its coil for it to sensibly remain energised all the time. Accidentally failing to isolate when you leave the car would result in returning to a flat battery.
There are electrically-operated remote latching isolators. These are used in commercial vehicles and are ideal for the job but they are expensive and overkill for your car. They only consume power while changing state from on to off and back again, not continuously, and they can be interlocked so that they will not switch off while the engine is running. see
https://cdn.shopify.com/s/files/1/0658/7343/files/ELBs.pdf?817
The best way to maximise starting and charging performance is to fit the largest, best battery that will fit the space, with an intelligent alternator controller if one is not already fitted. A larger battery scores in two ways - first, there is more capacity to serve low level background loads, which would otherwise be saved by the isolator. But when you come to start the engine, the battery has lower resistance and can deliver the starter current with less voltage drop, so even if the same percentage of discharge has occurred, the starter will get more volts for longer before the battery starts flagging. A 25% increase in capacity can make a very noticeable improvement in starting performance.