So im left with 4 options to get this install to comply.
1- TT the outbuilding
That is not going to protect the sub-main cable against a fault.
Already the building is safe internally as the RCBOs (and RCD incomer) will make sure all final circuits meet disconnection time no problem. The sub-main R2 is still going to be
way lower than any earth rod's Ra value!
2- time dealy rcd 100mA on the submain @ origin and possibly remove the time delay rcd in outbuilding and replace with standard 100A 2pole main switch.
I suspect the original designer might have been aware of the high R2 and aimed at protected the installation that way, but not the feed cable, alas.
Moving the delay RCD to the cable origin would solve those problems, but puts resetting it in a more inconvenient place. However with an all-RCBO board the chances of the supply delay-RCD firing should be very slim as practically all faults should be cleared by the RCBOs.
3 change the Swa submain (not gunna happen)
No, that really is a last-resort option and only justified if the volt drop or whatever was unacceptable.
4 run a parallel earth To bring disconnection times down.
If the cable is ducted or on tray, etc, so you think it is feasible to run a CPC alongside then it might be the best overall option as the out building would retain access to reset the delay RCD and no need to find space for another enclosure or whatever at the source end.
If you have the cable length & type and have checked the measured R2 is consistent with it, then it ought to be simple to compute the new R2 and then Zs with a CPC of, say, half the phase conductor size run along and see if it then meets a 5s disconnection limit.