For twin and earth, we meticulously make sure we keep track of the which side a particular core is on....
Just kidding of course
Since most of the cables we use have two cores plus an earth (or some other core), providing you can definitely identify one of the cores, using a continuity tester you can identify the others.
Join core 1 to the one you know and then go to the other end of the cable run and look for continuity between the one you know and the others... where you get continuity should be core 1. Rinse and repeat for other cores. If you don't have a known core you can use a long lead continuity test which uses a very long test lead connected to one end of the cable and then a normal lead at the other end to look for continuity on the cores.... this would typically be done with a low resistance ohm meter like the one built into most MFTs.
Hope this helps