So what is switching the boiler and you just said the grey was disconnected so the orange won't be letting anything throughjesus christ power up a 2 way valve switch live (brown) without the permanent live connected (grey) the valve will open and close as power connected and disconnected via stat, the orange will allow through whatever voltage is connected to the grey (usually 230) or in this case the volt free supply from boiler
So what is switching the boiler and you just said the grey was disconnected so the orange won't be letting anything through