99.99% this is indeed just static.
A shock caused by an electrical fault will be continuous - all the time you remain in contact and every time you touch the 'live' point, you will receive the shock. Static requires you to charge up your stray capacitance (to earth) by friction or some other means, during which the charging current is too small to notice although the ultimate voltage can be very high. Then, when you touch something earthed (or conductive and large in size which has a large stray capacitance to earth itself) your own stray capacitance discharges suddenly with a current that is large enough to feel. Then you feel nothing until you have charged yourself up again.
A good demonstration would be to get into a position where you would receive a shock from the switch but stand on an insulator such as a piece of dry wood or plastic before doing so. Your resistance to earth will then be guaranteed to be much too high to allow enough current to flow from a 230V electrical fault to be felt as a sudden shock. If you get the shock, then nothing, you have proven it was caused by your stray capacitance discharging.*
Your Zdb reading is good enough that there is no reason to suspect a disconnected CNE upstream, and there are none of the usual symptoms of the lights flickering and blowing and going very dim when anything else is turned on. It would not however manifest as a voltage between N & E within the system as they would still be connected together at the service terminals; rather between earth as defined by the equipotential zone in the house, and true earth outside. Your Zs at the switch also looks normal and indicative of a good enough earth that if there is a serious leakage or intermittent short from line, the OCPD will trip.
*Note incidentally that the stray capacitance of the body is high enough that you can sometimes detect a steady, faint tingle / buzz corresponding to a fraction of a milliamp of AC leakage if you brush lightly against a truly live metal surface, but that is not the effect described here.