As you would only require the lights to be work when the premises are occupied, I would opt for a master switch, that controlled the whole lighting. Rather than a time clock. First one in turns it on, last one out turns it off. Obviously any permenantly live feeds would have to to be separate.
Using a PIR to control the outside lights may cause problems, depending on the choice of lamps. It would be prefferable for the lamps to be lit before someone stepped outside to escape rather than having to wait for lamps to strike up before being able to see their escape route.
The escape route signs that glow in the dark, are really only usefull after they have had a chance to charge up, as such they would only be effective after how ever long it takes for them to charge.
Whereas the decals that can be affixed to the fittings are visable immediately.