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If the circuit has already been energised, and has been at full operating temp, then you can use the max values in BS7671.
for an initial verification you should apply the rule of thumb (x 0.8) this is to allow for the increase of resistance as the circuit warms up.
BS7671 assumes cable is at 70 C, when you test the cable will be at ambient temp, adjust the test figure by the factor.
It makes no odds energized or not you will need to make a correction to your test figures.