Thank you all for your prompt and useful replies.
I accept the point made by Rob about they can't include every device but I was surprised one as common as 45A wasn't there.
I understand that Cmin was introduced to allow a "safety factor" to the BS 7671 Zsmax values in consideration of possible supply voltage fluctuation i.e. the minimum voltage available may be as low as 95% of nominal (218.5V) under certain conditions.
We then use this min possible voltage divided by the operating current of the device, in this case 225A, to find the Zsmax which will ensure the device operates in the required disconnection time, even if the supply voltage is at its minimum. As per Marcus and Ian.
Moving onto the second bit of my query. This would be the "BS 7671 Zsmax value" to write in column 8 of the Schedule of Test Results if we follow the apparent meaning/spirit of the Regs? This value would still be subject to the 0.8 rule of thumb when comparing with measured test values. The footnote on the bottom of the schedule allows for values from other sources to be used if this is stated in column 25. An example could be taking an already corrected value from the OSG which still has the 45A Zs value listed.
I am not trying to be pedantic here but I am trying get to a correct firm procedure on how to deal with such issues. What is acceptable or not. I would agree totally with the logic of Marcus and Elecnewt, but it doesn't seem to fit with the intentions of the Regs. I am also thinking about lessening the confusion for those training in inspection and testing.
Thanks to all.