So as promised I eventually looked into this, it seems like we were both right!
I found an interesting thread on IET to explain IET Forums - Understanding the adiabatic equation - https://www.------.org/forums/forum/messageview.cfm?catid=205&threadid=65487&enterthread=y
The gist of it is for fuses the worst case is indeed as you state, where the I is lower the I2t will be higher, so you have to check the distant end.
However for MCBs the situation reverses when the magnetic trip comes into play - when the I is higher the I2t will be higher, so you have to check the head end instead.
Cheers, I learnt something today!
However, after all that, the OPs situation, as far as I can tell, he still needs to use the actual PEFC rather than the Cmin, and he still needs to use the head end and the tabulated I2t values due to the magnetic trip being relevant.
And also not forgetting that the other conductors are also subject to the same process - which may apply if PEFC and PSSC are not the same.