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Problems with aluminium wires
Aluminium wires have been implicated in house fires in which people have been killed.
[2][3] There were several possible reasons why these connections failed. The two main reasons were improper installation and the differences in
coefficient of expansion between aluminium wire and the terminations used in the 1960s.
Aluminium oxidation
Most metals (with a few exceptions, such as
gold) oxidize freely when exposed to air. Aluminium oxide is not an electrical
conductor, but rather an electrical
insulator. Consequently, the flow of
electrons through the oxide layer can be greatly impeded. However, since the oxide layer is only a few nanometers thick, the added resistance is not noticeable under most conditions. When aluminium wire is terminated properly, the mechanical connection breaks the thin, brittle layer of oxide to form an excellent electrical connection. Unless this connection is loosened, there is no way for oxygen to penetrate the connection point to form further oxide.
Coefficient of expansion
Aluminium's coefficient of expansion varies significantly from the metals common in devices, outlets, switches, and screws that were used before the mid-1970s. Many terminations of aluminium wire installed in the 1960s and 1970s continue to operate with no problems. However, many connections were not made properly when installed. Since the aluminium and steel both expand and contract at different rates under thermal load, these loose connections began to grow progressively looser over time. Likewise, a connection made with too much torque causes damage to the wire. Over time, this cycle results in the connection loosening slightly, overheating, and allowing intermetallic steel/aluminium alloying to occur between the conductor and the screw terminal. This results in a high-resistance junction, leading to additional overheating. Although many believe that oxidation was the issue, studies have shown[
citation needed] that oxidation was not significant in these cases.
Joining aluminium and copper wires
Terminals joining aluminium wires to copper wires
Result improperly joined aluminium and copper wires in old USSR apartments, done by qualified electrician
Another issue is the joining of aluminium wire to copper wire. As aluminium and copper are dissimilar metals,
galvanic corrosion can occur in the presence of an electrolyte and these connections can become unstable over time. Special connectors have been designed for the purpose of joining aluminium to copper wire, such as the Marrette No. 63 and No. 65 and the Ideal Twister No. 65. These twist-on wire connectors use a special antioxidant paste to prevent corrosion of the connection.
At least one manufacturer, AlumiConn, offers UL/CSA listed lug type connectors similar to those used for larger gauge aluminium-aluminium and aluminium-copper connections for branch circuit size wiring.
[4] These would appear to make a more reliable connection on the aluminium wire with its higher coefficient of expansion than wire nut-type connectors. These may have the same problem with enclosure space as the COPALUM system (described under "Upgrading aluminium-wired homes"). A listed connector should always be used for connecting aluminium to copper wire.
Although aluminium wire smaller than 8 AWG is not used in new house wiring, lots of aluminium wires are used all over North America. The larger sizes offer excellent options for terminations, since the most common termination in larger sizes is a dual-rated lug made of an aluminium alloy. Properly terminated aluminium wiring should be regarded as safe, since long-term installations have proven its reliability. Aluminium wire is often used in residential applications for service entrance and large branch circuit loads such as ranges and air-conditioning units.
Hazard insurance
In some states, home hazard insurance will not cover homes with aluminium wiring, and some insurance companies that claim to cover it charge a higher premium than for homes with copper wiring. Reputable and knowledgeable insurers should recognize the difference between AA-8000 series aluminium building wire and that used prior to 1972.