A 100mA RCD might trip before a 30mA RCD depending on the type of fault and the characteristics of the RCDs.
To ensure discrimination the 100mA RCD would need to be time delayed i.e type S.
If I were installing I might tend to go for an upfront time delayed 100mA RCD and then a split load Dual RCD board, though obviously RCBOs would be better if you can get them in double pole versions.
If you had good Ufer earthing and the resistance to earth was then low enough to trip your MCBs then you would be OK with just RCBOs.
To ensure discrimination the 100mA RCD would need to be time delayed i.e type S.
If I were installing I might tend to go for an upfront time delayed 100mA RCD and then a split load Dual RCD board, though obviously RCBOs would be better if you can get them in double pole versions.
If you had good Ufer earthing and the resistance to earth was then low enough to trip your MCBs then you would be OK with just RCBOs.