There is no mention of a 100mA time delayed RCD in the 17th, except in Appendix 3 (Page 243) to give disconnection times. Its used as a solution for RCD discrimination, whereby the RCD closest to the fault will trip before anything else trips. The time delay gives a 30mA RCD 100ms to trip, if not it trips itself.
A 30mA RCD should trip within 300ms for a 30mA fault (which wouldn't disturb the 100mA RCD), or the 30mA RCD should trip within 150ms for a 60mA (x2) fault, so this could make the 100ms RCD react, but for a 150mA (x5) fault the 30mA RCD should definetly trip within 40ms, if not the 100mA should trip!
RCDs outside Additional protection and the other requirements of a 30mA RCD are used when the potential fault current is not enough to trip an overcurrent device (eg. fuse or MCB)
A 30mA RCD should trip within 300ms for a 30mA fault (which wouldn't disturb the 100mA RCD), or the 30mA RCD should trip within 150ms for a 60mA (x2) fault, so this could make the 100ms RCD react, but for a 150mA (x5) fault the 30mA RCD should definetly trip within 40ms, if not the 100mA should trip!
RCDs outside Additional protection and the other requirements of a 30mA RCD are used when the potential fault current is not enough to trip an overcurrent device (eg. fuse or MCB)