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davesparks
If you are rewiring the property, why not just stick 10mm bonding in and a 16mm main earthing conductor. either reposition the earth rod and see if you get a better Ra value or add another until you get a better value, If I was rewiring the property I would be inclined to install my own rod anyway as for all you know the rod that's already been installed could of been cut down in size as hit hard ground etc when it was installed.
Because that would be a waste of time and money if only 6mm is required, you might as well install 2.5mm for lighting and 16mm for cooker supplies if you are going to use that logic .
Why are you talking of installing a rod in the singular? That won't achieve anything useful, at least 2 electrodes made up of at least 2 rods coupled together would be a good starting point.