Your supply is 'three phase 2 wire corner grounded delta' as in the diagram above but your line voltage is 225V (ish) instead of the 480V this diagram shows.
So in your home A is L1 and C is L2 and B is the earthed phase/line/neutral N.
Single phase supplies are derived by connecting between pairs of lines A-B, A-C and B-C.
Your UFH uses all these pairings to 'spread' the loading over the three lines/phases since this is a large long duration power demand and makes best use of capacity of the three lines to your home.
I did not delve into how all your other home final circuits are wired eg: lighting and sockets but I strongly suspect they are connected A-B thus L1-N, and B-C thus L2-N so that single pole switching may be used in the line/phase only because only L1 and L2 are at 225V wrt to N and E.... and N is at a low voltage wrt to E - I think we measured 20V ish.
When L1 and L2 are used the switching must be double pole as you have gathered from the contactor contacts wiring for the UFH because both lines are at 225V wrt to N and E.