If you look at the side of the valves there's a manual override. When it's energised you will see it move. You can force it on by pushing it to the open position and holding it up while it tries to close on the spring.
If they are both operating as expected mechanically and you are getting voltage on the orange with the valve in the closed position you have a faulty auxiliary switch which might have been what the electrician was referring to.
If they are both operating as expected mechanically and you are getting voltage on the orange with the valve in the closed position you have a faulty auxiliary switch which might have been what the electrician was referring to.