You could really do with a double check valve on the DHW exit from the Hex to stop potential reverse flow in the event of S1 failing.
You should also consider a potable water expansion vessel on the DHW Hex loop as you do have a closed volume of water (I know it's less than 15 ltrs)
AND (apart from the fact that you should should budget for a new boiler in the near future ..) Although they wont admit it, the way your boiler works it should cope with pre-heated water:
I believe The GlowWorm's thermistor is on outlet of hot and flow switch on inlet.
So it should require no mods to boiler. She's not allowed over 65 and the Thermistor will shut out burner once at 58. So initially to combi will flick in but then it will drop out as the store pre heats. As you've done, heat the store to max of 85c run it across plate so the plates always hot and ready to go - use one of those grunny smart pumps with a remote pocket stat on hot outlet on plate. Bring cold via a double check into plate then tmv down on to DCW inlet on boiler at max of 65c (or 45° as you're already doing though in that case the boiler will probably fire up to continue heating...)
Unfortunately Glowworms don't have the best rep on the market, so when it comes time (probably in the not to distant future
) to replace it, better to consider and Intergas, Atag, Ideal Logic + or a Baxi Duo-tec 2 as I'm pretty sure all of those can take pre-heat.
If you don't want to run the risk of trying the preheat on your existing boiler, rather than shutting off the HEX completely, you could also blend down the heating INPUT to the HEX using an underfloor heating thermostatic blending valve myson do one so you recycle a proportion of the output from the hex back to the input so reduce the temperature of the inflow.
(p.s. for anyone else considering something similar get hold of a Baxi 105E and rip its guts out - almost all the components you need are lurking in there somewhere, including a nice pcb with a variable pump speed controller )
Beware unless you are GSR you must not touch the insides of the boiler.....